Yaa Fabric Fibers: Sources, Chemic Composition
Thursday, 13 December 2018
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Types, Sources in addition to Chemical Composition of Textile Fibers
Jay Sanjay Trivedi
Dept of Textile Engineering
Government Polytechnic Nagpur, Republic of Republic of India
Email: trivedij006@gmail.com
Jay Sanjay Trivedi
Dept of Textile Engineering
Government Polytechnic Nagpur, Republic of Republic of India
Email: trivedij006@gmail.com
SOURCES OF CELLULOSIC FIBERS:
Classification of fiber according to cellulosic sources are given below.
1. SEED HAIR FIBERS:
The seed hairs similar cotton incorporate cellulose amongst really less non cellulosic meat (4-12%). This makes purification virtually simpler than for virtually of other cellulosic fibers. Other seed fibers are kapok in addition to bombax cotton. These fibers incorporate 55-65% cellulose.
2. BAST FIBERS:
The Bast fibers are long fibers of the outer bark of the diverse plants. It includes FLAX, HEMP, JUTE, RAMIE, KENAF, SUNN etc.. the fibers are integrated amongst natural paste inward the found structure. The fibers are separated past times removal of the gums in addition to the procedure is by in addition to large known every bit RETTING.
Fig: Textile fibers |
Many of the celluslosiv fibers similar SISAL, HEMP, MANILA are every bit good obtained from the leaves of the plants. The fibers extend longitudinally the sum length of the leafage in addition to contribute forcefulness to the leaves. The fibers are buried inward tissues of the leaves in addition to tin live separated from the tissue past times scrapping since at that topographic point is no bonding betwixt the fibers in addition to the tissue. This procedure is known every bit DECORTIFICATION.
4. HASK OR FRUIT FIBERS:
The husk of coconut, betelnut,and palmnut which protect the fruit for evolution tin live processed in addition to utilize every bit a fiber. After removal of the fruit the husk tin live extyracted, retted, in addition to processed.
SOURCES OF PROTEIN FIBERS:
Sr. No | Fibers | Sources |
1. | Wool | From Sheep |
2. | Mohair | From Angara Goat |
3. | Cashmere | From Cashmere Goat |
4. | Camel Hair | From Camel |
5. | Rabbit Hair | From Rabbit |
6. | Horse Hair | From Horse |
7. | Alpaca, Ilama | Ilama |
SOURCES OF SYNTHETIC:
Main sources of formation of synthetic fibers are:
- PETROLEUM
- NATURAL GAS DEPOSIT
- COAL
- High resistance to chemicals
- High resistance
- Low flammability
- High elasticity in addition to and then high resistance to distortion in addition to creasing.
- High resistance to abrasion.
Sr.No | Chemicals | Monomers |
1. | Methane | Vinyl Chloride Vinyl Acetate Acrylonitrile Hexamethylene Diamine |
2. | Ethane | Vinyl Chloride |
3. | Ethylene | Ethylene Ethylene Glycol Vinyl Chloride Acrylonitrile Hexamethylene Diamine Styrene |
4. | Propylene | Propylene Acrylonitrile |
5. | Proprane/Butane | Ethylene Propylene |
6. | Butadiene | Hexamethylene Diamine |
7. | Benzene | Adipic Acid Hexamethylene Diamine Caprolactum |
8. | Phenol | Terephathalic Acid Hexamethylenediamine |
CLASSIFICATION OF POLYMER:
Sr.No | Monomer Characteristic | Type Of Polymer |
1. | Functionality Of The Monomer | Linear Polymer, Branched Polymers, Or Cross Linked Polymers. |
2. | Chemical Characteristic Of The Monomers | Addition Polymers Or Condensation Polymers. |
3. | Chemical Groups Present In Condensation Polymers | Polymer Named As Per The Chemical Group E.G Polyamides, Polyethylene |
4. | No. Of Monomers Used | Homo-Polymer Or Co-Polymer |
| | |
The principal characteristics of fiber forming polymer:
- Flexibility
- Molecular Mass
- Configuration
- Crystallinity
- Orientation
Sr.No | Method Of Spinning | Polymer | Chemical Nature |
1. | Melt Spinning | Nylon Polyester Polyethylene Polypropylene | Polyamide Poly(Ethylene Terephtalate) Ethylene Homo And Co-Polymer Propylene Homo And Copolymer |
2. | Dry Spinning | Cell Acetate Vinyon | Acetylated Cellulose Vinyl Chloride And Vinyl Acetate Co-Polymer Poly(Acrylonitrile) |
3. | Wet Spinning | Viscose Casein Acrylin Vinylon Pvc | Cellulose Protein Poly(Acrylonitrile) Polyvinyl Alcohol Polyvinyl Chloride |
DENSITY METHOD:
Volume fraction crystallinity tin live calculated past times using next equation:
Xv(%) = do-da/dc-da*100
where,
Xv = is the book fraction crystallinity.
do = the density of the experimental sample.
dc = the density of pure crystalline area.
da = the density of pure amorphous area.
The volume fraction crystallinity tin live measured from the specific book information. This equation is:
Xm(%) = Va-Vo/Va-Vc*100
where,
Xm = is the volume fraction crystallinity.
Vo = the specific book of the experimental sample.
Va = the specific book of pure amorphous expanse in addition to
Vc = the specific book of pure crystalline area.
This equation tin live modified inward damage of density every bit V=1/D
Xm(%)= dc/da*do-da/dc-da*100
where,
dc = the densities of pure crystalline area.
da = the densities of amorphous area.
Density of pure crystalline in addition to pure amorphous areas:
Sr.No | Fibers | Dc(G/Cc) | Da(G/Cc) |
1. | Polyethylene | 1.000 | 0.852 |
2. | Polypropylene | 0.937 | 0.854 |
3. | Poly(Ethylene Terephthalate) | 1.455 | 1.335 |
4. | Poly(Butylene Terephthalate) | 1.396 | 1.280 |
5. | Polyamide 6 | 1.230 | 1.089 |
6. | Polyamide 6.6 | 1.220 | 1.069 |
Sr.No | Liquid | Density(gm/m) |
1. | Ethanol | 0.79 |
2. | Isopropanal | 0.79 |
3. | Methanol | 0.80 |
4. | Xylene | 0.86 |
5. | Toluene | 0.87 |
6. | Benzyl Alcohol | 0.92 |
7. | Water | 1.00 |
8. | Diethylene Glycol | 1.11 |
9. | Sodium Bromide | 1.41 |
10. | Carbon Tetrachloride | 1.59 |
11. | Calcium Nitrate | 1.60 |
12. | 1,3-Dibromopropane | 1.99 |
13. | Ethylene Bromide | 2.18 |
14. | Bromoform | 2.89 |
Sr.No | Cellulose | Alfa | Beta | C | Beta |
1. | Cellulose i | 8.35 | 10.3 | 7.9 | 84 |
2. | Cellulose ii | 8.10 | 10.3 | 9.1 | 62 |
3. | Cellulose iii | 7.74 | 10.3 | 9.9 | 58 |
4. | Cellulose iv | 8.11 | 10.3 | 7.9 | 90 |
5. | Types Of Bond | Hydrogen | Co-Valent Vander Walls | | |
6. | Stability(Kcal/Mole) | 15 | 50 | 08 | |
Sr.No | Types Of Hydrates | Hydrodynamic Diameter(Mm) | Concentration Of | ||
| | | NaOH (%) | KOH (%) | LiOH (%) |
1. | Dipole Hydrate | 0.5-0.8 | 30-70% | 40-75% | 20-60% |
2. | Solvated Dipole Hydrate | 0.8-1.0 | 16-30% | 30-40% | 9-20% |
3. | Hydrated Ion Pair | 1.0-1.5 | 6-15% | 7-30% | 5-6% |
Sr.No | Commercial Cotton | Staple Length |
1. | Sea Island Cotton | Around v cm |
2. | Egyptian Cotton | Between 3.7-4.5 cm |
3. | Brazilian Cotton | Between 3-4 cm |
4. | American Cotton | Between 2.5-3.5 cm |
5. | Indian Cotton | Between 2-3 cm |
6. | Communist People's Republic of China Cotton | Between 1.5-2 cm Only |
Sr.No | Chemicals | Composition (%) |
1. | Cellulose | 88-97% |
2. | Protein | 1-2% |
3. | Oil And Wax | 0.4-1.5% |
4. | Pectins | 0.4-1.5% |
5. | Minerals | 0.7-1.6% |
6. | Others | 0.5-8.0% |
Sr.No | Fibers | Cellulose | Hemicellulose | Lignin | Pectin | Wax | Ash | Others |
1. | 1.Seed Hair Fibers: Cotton Kapok | 93.0 64.0 | 2.6 23.0 | 13.0 | 0.9 23.0 | 0.6 | 1.2 | 1.7 |
2. | Bast Fibers: Jute Flax Ramie | 71.5 71.2 74.4 76.2 | 13.3 18.6 17.9 14.6 | 13.1 2.2 3.7 0.7 | 0.2 2.0 0.8 2.1 | 0.6 2.3 0.8 0.3 | 1.0 1.3 | 0.3 2.6 2.3 6.1 |
3. | Leaf Fibers: Sisal Pineapple /Manila Hemp | 73.1 70.2 | 13.3 21.8 | 11.0 5.7 | 0.9 0.6 | 0.3 0.2 | | 1.4 1.5 |
4. | Husk Fibers: Coir | 44.2 | 0.8 | 45.8 | 4.0 | | | 5.2 |
Duration of retting of JUTE FIBERS:
Sr.No | Process | Duration |
1. | Dew Retting | 7-15 Days |
2. | Stagnant Water Retting | 10-20 Days |
3. | Running Water Retting | 22-30 Days |
4. | Chemical Retting | 6-8 Days |
Duration of retting of FLAX FIBERS:
Sr.No | Process | Duration |
1. | Dew Retting | 10-20 Days |
2. | Stagnant Water Retting | 30-40 Days |
3. | Running Water Retting | 20-30 Days |
Composition of proteins inward dissimilar Fibers:
Sr.No | Proteins | Composition(%) |
1. | Carbon | 45-55% |
2. | Hydrogen | 6-8% |
3. | Oxygen | 19-30% |
4. | Nitrogen | 15-20% |
5. | Others | 0-5% |
Different chemicals inward Silk:
Sr.No | | Mulberry Silk | Tassar Silk | Muga Silk | Eri Silk |
1. | Fibroin | 70-80% | 80-90% | 80-90% | 80-90% |
2. | Sericine | 20-30% | 8-10% | 8-10% | 4-5% |
3. | Other | 2-3% | 3-5% | 3-9% | 3-5% |
Sr.No | | Fibers(%) | Sericine(%) |
1. | C | 47.6% | 46.5% |
2. | H | 6.4% | 6.0% |
3. | N | 18.3% | 16.5% |
4. | O | 27.7% | 31.0% |
The fibroin i.e the principal business office of silk is made upward serial of dissimilar amino acids. The virtually of import is SERICINE, ALANINE in addition to GLYCINE. The of import acids are:
Sr.No | | % |
1. | Glycine | 36.8% |
2. | Alanine | 22.2% |
3. | Serine | 11.4% |
4. | Tyrosine | 11.1% |
5. | Leucine | 1.5% |
6. | Proline | 1.0% |
7. | Valine | 2.7% |
8. | Phenytalanine | 1.5% |
9. | Histidine | 0.1% |
10. | Lysine | 0.2% |
11. | Threonine | 1.3% |
12. | Arginine | 0.9% |
Sr.No | | % |
1. | Glycine | 20-30% |
2. | Alanine | 35-40% |
3. | Serine | 10-15% |
4. | Tyrosine | 8-10% |
5. | Arginine | 9-13% |
6. | Threonine | 5-10% |
7. | Lysine | 5-7% |
Sr.No | | Mulberry Silk | Wild Silk |
1. | Lysine | 20-30% | 20-30% |
2. | Serine | 16-20% | 7-16% |
3. | Glycine | 8-10% | 10-20% |
4. | Aspartic Acid | 8-12% | 7-10% |
5. | Glumatic Acid | | 4-6% |
6. | Arginine | | 5-15% |
7. | Threonine | 4-6% | 3-10% |
8. | Histidine | 4-6% | 3-6% |
9. | Tyrosine | | 4-6% |
TEXTILE FIBER DENSITIES:
Sr.No | Textile Fibers | Fiber Densities (g/cm3) |
1. | Cotton | 1.54 |
2. | Flax | 1.50 |
3. | Jute | 1.50 |
4. | Wool | 1.30 |
5. | Silk | 1.60 |
6. | Polyester | 1.22 |
7. | Viscose | 1.53 |
8. | Cuprammonium | 1.53 |
9. | Polyurethane | 1.15 |
10. | Polypropylene | 0.90 |
11. | Polyethylene | 0.92 |
12. | Nylon 6 | 1.13 |
13. | Nylon 66 | 1.14 |
14. | Acrylic | 1.14-1.17 |
15. | Polyvinyl Alcohol | 1.30 |
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